Search results for " EIS"
showing 10 items of 20 documents
L’utilisation du clou dans l’architecture aux IIe-Ier siècles av. J.-C. : technologie, typologie, conservation, fréquence
2016
International audience
Il Progetto ATENA: Applicazione di metodologie innovative per la conservazione di manufatti metallici e ceramici da scavo archeologico e per il recup…
2007
Qui di seguito viene illustrato il progetto scientifico ATENA, svolto presso l'Istituto per lo Studio dei Materiali Nanostrutturati (ISMN) del Consiglio Nazionale delle Ricerche (CNR) e co-finanziato dal MIUR con Decreto Direttoriale 9-10-2002, n. 1105/2002. Il progetto si propone di applicare avanzate tecniche diagnostiche strumentali al fine di acquisire la dettagliata conoscenza microchimica e microstrutturale di manufatti metallici e ceramici antichi, di definirne il meccanismo di alterazione e/o degrado e di progettare, sintetizzare e validare opportuni prodotti e formulazioni per il restauro conservativo di tali manufatti. Le conoscenze acquisite sono utilizzabili anche per il recuper…
Assessing the Performance of the Italian Translations of Modified MEIM, EIS and FESM Scales to Measure Ethnic Identity: A Case Study
2023
Measuring the ethnic identity of linguistic minorities is a research problem which can be tackled departing from a clear operational definition of the construct. This paper will present the performance of the Italian translations of various scales widely used in the relevant literature, which have been modified for the aims of this study and used in research conducted in 2016 in the ArberesheMunicipalities of Piana degli Albanesi and Santa Cristina Gela (Province of Palermo). These scales consist of modifications of the Multigroup Ethnic Identity Measure (MEIM), Ethnic Identity Scale (EIS) and Familial Ethnic Socialization Measure (FESM). The psychometric properties were analysed for all th…
Recent advances on physico-chemical characterization of passive films by EIS and differential admittance techniques
2007
Abstract Thin Nb2O5 anodic films (∼20 nm thick) grown in phosphoric acid solution have been characterised by EIS and differential admittance study in a large range of potential and frequency. The overall electrical behaviour has been interpreted by means of the theory of amorphous semiconductor Schottky barrier in presence of a non-constant density of states (DOS). A comparison of DOS for films grown in different electrolytes is reported.
Photoelectrochemical monitoring of rouging and de-rouging on AISI 316L
2017
Electrochemical conditions for inducing rouging on surface of AISI 316L in quasi neutral aqueous solution are studied. Potentiostatic polarization at 0.6 V vs. SSC at pH ∼ 7 allowed growth of colourless passive films with a band gap slightly lower than that estimated for the oxide grown on the SS surface by air exposure due to chromium dissolution. Under stronger anodic polarization (UE = 1.5 V vs. SSC) coloured passive films are formed, mainly constituted by iron oxide according to their band gap (Eg = 2.0 eV). Etching in citric acid at 60 °C results to be effective in removing rouging.
Semiconducting properties of passive films and corrosion layers on weathering steel
2020
Abstract Anodic films were grown on Weathering Steel by potentiostatic polarization in slightly alkaline solution. The photoelectrochemical results reveal that they are n-type iron oxide with Eg = 2.0 eV. Rust layer grown by atmospheric corrosion are n-type semiconductors with a band gap higher than that estimated for the anodic film attributed to the formation of γ-lepidocrocite. The electrochemical impedance spectra allow to evidence that rust layers have a higher conductivity with respect to anodic films due to the presence of highly doped iron oxide layers. The use of Mott-Schottky theory to model the dependence of oxide capacitance as function of potential is critically discussed.
Local electrochemical impedance spectroscopy study of the influence of ageing in air and laser shock processing on the micro-electrochemical behaviou…
2011
International audience; In the present paper, the micro-electrochemical behaviour of AA2050-T8 in 0.1 M NaCl was first studied after polishing by means of local electrochemical impedance spectroscopy and field-emission scanning electron microscopy/electron dispersive spectroscopy (FE-SEM/EDS). The influence of ageing in air and LSP was then investigated. Ageing in air for three months led to an increase in the charge transfer resistance. This was clearly observed in sites surrounding constituent particles where the charge transfer resistance was in the order of 1 MΩ cm2 (instead of 10-3 MΩ cm2 after polishing). Increased passivity around particles was confirmed from FE-SEM/EDS analysis. On …
Electrochemically-induced TiO2 incorporation for enhancing corrosion and tribocorrosion resistance of PEO coating on 7075 Al alloy
2018
Abstract 7075 Al alloy was PEO-treated in a silicate based electrolyte containing 3 g l-1 potassium titanyl oxalate using unipolar and bipolar pulsed current waveforms. The coating formed by the bipolar waveform with the wider cathodic pulses showed volcano-like surface morphology with no evidence of large pores at the metal/coating interface. It revealed the highest corrosion performance due to the synergistic effect of TiO2 incorporation and structural/morphological features along with a better passivation behavior indicating no pitting susceptibility. For this coating, the tribocorrosion tests showed no potential drop during sliding under 1 N with the lowest volume loss of 0.022 mm3.
Photocurrent and Impedance Spectroscopy Studies on Electrodeposited Polypyrrole
2008
Złudna idea de(kon)strukcji architektury
2017
Artykuł jest polemiką z poglądami dwóch XX-wiecznych architektów: Petera Eisenmana i Bernarda Tschumiego, którzy w związku, ale też i poza filozoficzną ideą dekonstrukcji Jacques’a Derridy rozwijali własny zamysł zdekonstruowania architektury. Sięgając do historycznych „korzeni” architektury i korzystając z opracowania Cezarego Wąsa na temat dekonstrukcji w architekturze, autor pokazuje, że zaprezentowana przez tych architektów idea jest złudna, gdyż rozmija się z istotą architektury i prowadzi do destrukcji tej formy sztuki.